4,4’-Dimethyl-2,2’-bipyridyl 4,4’-二甲基-2,2’-联吡啶

CAS 1134-35-6 MFCD00006441

化学结构图

1134-35-6
SMILES: Cc1ccnc(-c2cc(C)ccn2)c1

化学属性

Mol. FormulaC12H12N2
Mol. Weight184.24
Density1.06
Melting Point169-174
TSCAYes
Appearance white to off-white pwdr.

别名和识别编码

Chemical Name4,4’-Dimethyl-2,2’-bipyridyl
MDL NumberMFCD00006441
CAS Number1134-35-6
EC Number214-483-2
Beilstein Registry Number128995
Synonym 2,2'-BI-4-PICOLINE 2,2'-Bi(γ-picoline) 2,2'-DI-4-PICOLYL 2,2'-联-4-甲基吡啶; 2,2′-二(γ-甲基吡啶) 4,4′-二甲基-2,2′-二吡啶 2’-Bipyridine,4,4’-dimethyl-2 4,4'-dimethyl-2,2'-bipyridine 4,4'-DIMETHYL-2,2'-BIPYRIDINE 4,4'-DIMETHYL-2,2'-BIPYRIDYL 4,4'-DIMETHYL-2,2'-DIPYRIDYL 4,4'-DIMETHYL-2,2'-DIPYRIDYL, SUBLIMED & 4,4'-Dimethyl-2,2'-dipyridine 4,4'-Dimethyl-2,2'-dipyridyl 4,4′-Dimethyl-2,2′-bipyridine 4,4′-二甲基-2,2′-联吡啶 Bipicoline,98% TIMTEC-BB SBB008769
PubChem Substance ID14338
Reaxys-RN128995
Chemical Name Translation4,4’-二甲基-2,2’-联吡啶
InChIKeyNBPGPQJFYXNFKN-UHFFFAOYSA-N
Wiswesser Line NotationT6NJ D1 B- BT6NJ D1
LabNetwork Molecule IDLN00222028
InChIInChI=1S/C12H12N2/c1-9-3-5-13-11(7-9)12-8-10(2)4-6-14-12/h3-8H,1-2H3
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分类

  • {SNA} ATRP, ATRP Ligands, Building Blocks, C12, Chemical Synthesis, Heterocyclic Building Blocks, Materials Science, Polymer Science, Pyridines, Reagents for Controlled Radical Polymerization, Reagents for Polymerization
  • {SNA} Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy, 分析/色谱,
  • {SNA} ATRP,
  • {SNA} ATRP, ATRP Ligands, Building Blocks, C12, Chemical Synthesis, Heterocyclic Building Blocks, Polymer Science, Pyridines, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, 材料科学
  • {SNA} Building Blocks,

产品应用

  • 合成蓝色发光分子的起始物质,在43%的量子场和450 nm激发。

相关文献及参考

  • Beilstein:23(3/4)1390

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSDW1765000
Hazard Codes Xn Xi Xi,Xn
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 78700 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOXIA6 Toxicon.  (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW,
   UK)  V.1-    1962-  Volume(issue)/page/year: 23,815,1985

其他信息

  • 4,4'-二甲基-2,2'-联吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp300047 4,4-二甲基-2,2-联吡啶 1g 220元 2011/04/16 B0852 4,4'-二甲基-2,2'-联吡啶 4,4'-Dimethyl-2,2'-bipyridyl 1G 626元 2011/04/16 B0852 4,4'-二甲基-2,2'-联吡啶 4,4'-Dimethyl-2,2'-bipyridyl 5G 2140元
  • 图谱信息:4,4'-二甲基-2,2'-联吡啶(1134-35-6)红外图谱(IR1) 4,4'-二甲基-2,2'-联吡啶(1134-35-6)核磁图( 1 HNMR) 4,4'-二甲基-2,2'-联吡啶(1134-35-6)红外图谱(IR2) 4,4'-二甲基-2,2'-联吡啶(1134-35-6)质谱(MS) 4,4'-二甲基-2,2'-联吡啶(1134-35-6)核磁图( 13 CNMR)
  • TCI Shanghai:4,4'-二甲基-2,2'-联吡啶 2,2'-Bi-4-picoline,>;98.0%(T)(1134-35-6)
  • Alfa Aesar:4,4'-二甲基-2,2'-联吡啶,98% 4,4'-Dimethyl-2,2'-bipyridine, 98%(1134-35-6)
  • Sigma Aldrich:1134-35-6(sigmaaldrich)
  • MOL 文件:1134-35-6.mol
  • Acros Organics:4,4'-二甲基-2,2'-联吡啶 4,4'-Dimethyl-2,2'-bipyridyl, 99+%(1134-35-6)
  • 检测方法:HPLC,NMR
  • 用途一:合成蓝色发光分子的起始物质,在43%的量子场和450 nm激发。

系列性分类


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