Butyltin trichloride 丁基三氯化锡

CAS 1118-46-3 MFCD00000515

化学结构图

1118-46-3
SMILES: CCCC[Sn](Cl)(Cl)Cl

化学属性

Mol. FormulaC4H9SnCl3
Mol. Weight282
Density1.693
Refractive index1.5210 to 1.5250
Flash Point81°C(lit.)
TSCAYes
Boiling Point93°C/10mmHg(lit.)
Melting Point-63°
Solubility可溶
Stability对湿度敏感

别名和识别编码

Chemical NameButyltin trichloride
Synonym Monobutylzinntrichlorid butyltrichloro-stannan N-BUTYLTRICHLOROTIN 三氯丁基锡 N-BUTYLTIN TRICHLORIDE Trichlorobutyltin Chlorid n-butylcinicity chloridn-butylcinicity(czech) Stannane, butyltrichloro- {uni_hambu Butyltrichlorotin; Butyltrichlorostannane Monobutyltin trichloride Butyltrichlorostannane 丁基三氯化锡(烷) mono-n-butyltin trichloride Trichlorobutylstannane 三氯化丁基锡 trichlorobutyl-stannan 三氯丁锡 monotributyltintrichloride 单丁基三氯化锡 丁基三氯化锡 Butylzinntrichlorid TRICHLORO-N-BUTYLTIN Butyltrichlorotin Butyltrichlorzinn 正丁基三氯化锡 butylst
MDL NumberMFCD00000515
CAS Number1118-46-3
EC Number214-263-6
PubChem Substance ID253661454
Beilstein Registry Number3535350
Chemical Name Translation丁基三氯化锡
Wiswesser Line NotationG-SN-G&G&4
Reaxys-RN3535350
LabNetwork Molecule IDLN00193170
InChIInChI=1S/C4H9.3ClH.Sn/c1-3-4-2;;;;/h1,3-4H2,2H3;3*1H;/q;;;;+3/p-3
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotin Halides

相关文献及参考

  • Short: III/35D5
  • Short: III/20a
  • Merck: 14,10455 Beilstein: 4,IV,4346
  • Merck: 14,10455

安全信息

RTECSWH6780000
Packing GroupII
UN Number 3265 UN 3265 8/PG 2 UN3265
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R37 Irritating to respiratory system 刺激呼吸道
  • R50/53
  • R20 Harmful by inhalation 吸入有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R48/23/25
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Storage condition Moisture Sensitive
GHS Symbol
WGK Germany1
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302+H312+H332
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes C C,Xn,N 8
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2140 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1245,1986

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 5 mg/tube
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 280,195,1992

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/tube
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,265,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3 gm/kg
SEX/DURATION            : female 7-8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 15,297,1995

其他信息

  • 可燃性危险特性:热分解排出有毒氯化物烟雾
  • 储运特性:库房通风低温干燥
  • 毒性分级:中毒
  • Acros Organics:三氯丁基锡 Butyltin trichloride, 97%(1118-46-3)
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:n-Butyltin trichloride, 96%(1118-46-3)
  • MSDS 信息:Butyltin trichloride(1118-46-3).msds
  • 下游产品:2-溴甲基-四氢吡喃
  • 丁基三氯化锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 191205000 丁基三氯化锡 Butyltin trichloride 97% 500 GR 2756元 2010/06/21 191201000 丁基三氯化锡 Butyltin trichloride 97% 100 GR 800元 2010/05/25 71125 n-Butyltin trichloride, 96% 25g 253元
  • 上游原料:四丁基锡
  • 外观:无色或微黄色液体。
  • Sigma Aldrich:1118-46-3(sigmaaldrich)
  • 职业标准:TWA 0.1 毫克(锡)/立方米; STEL 0.2 毫克/立方米 (皮肤)
  • 灭火剂:水, 干粉, 二氧化碳, 泡沫
  • 急性毒性:口服-大鼠 LD50: 2140 毫克/公斤
  • 类别:有毒物质
  • TSCA:Yes
  • 用途二:丁基三氯化锡(1118-46-3)是一种PVC稳定剂的重要中间体,主要用于玻璃容器表面的热端涂层。啤酒瓶热端喷涂液。
  • MOL 文件:1118-46-3.mol
  • 用途一:用作生产玻璃制品的增强剂
  • 刺激数据:皮肤-兔 0.75 毫克/24小时 重度; 眼睛-兔 0.05 毫克/24小时 重度

系列性分类


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