Omethoate O,O-二甲基-S-(N-甲基氨基甲酰甲基)硫代磷酸酯

CAS 1113-02-6 MFCD00055441

化学结构图

1113-02-6
SMILES: CNC(=O)CSP(=O)(OC)OC

化学属性

Mol. FormulaC5H12NO4PS
Mol. Weight213
Density1.0
Flash Point100 °C
Solubility不溶于石油醚，微溶于乙醚，可混溶于水乙醇、烃类等。

别名和识别编码

Chemical NameOmethoate
CAS Number1113-02-6
Synonym MODERN O,O-DIMETHYL-S-METHYLCARBAMOYL METHYL-PHOSPHOROTHIOATE {ALD BAYER 45,432 O,O-dimethyl S-methylcarbamoylmethyl phosphorothioate Omethoat (ISO) Dimethoate PO isologue {Chemicalbook} Dimethoate Oxygen analog Dimethoate oxygen analog bay 45432 O,O-Dimethyl S-[(methylcarbamoyl)methyl] phosphorothioate O,O-Dimethyl S-methylcarbamoylmethyl phosphorothioate; BAY 45432; Dimethoate oxon; Dimethoxon; Folimat FOLIMAT O,O-Dime Omethoate 氧化乐果原油(70%) { Bayer 45432 Acetamide, 2-mercapto-N-methyl-, S-ester with O,O-dimethyl phosphorothioate O,O-dimethyl-S-methylcarbamoy Phosphorothioic Acid O,O-dimethyl S-[2-(methylamino)-2-oxoethyl]ester bayers-6876 O,O-二甲基-S-[2(甲氨基)-2-氧代乙基]硫代磷酸 Phosphorothioic acid, O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] ester O,O-二甲基S-甲基氨基甲酰基甲基硫赶磷酸酯 Phosphorothioic acid, O,O-dimethyl ester, S-ester with 2-mercapto-N-methylacetamide OMETHOAT 氧化乐果 OMETHOATE O,O-dimethyl S-(N-methycarbamoylmethyl)phosphorodithioate FOLIMAT(R) O,O-DIMETHYL S-(N-METHYLCARBAMOYLMETHYL) PHOSPHOROTHIOATE 蚧毕丰乳油 PHOSPHOROTHIOIC ACID, O,O-DIMETHYL S-[2-(METHYLAMINO {uni_hambur DIMETHOATE-O-ANALOG Dimethoxon dimethoxon Spraymate L 1700 omethoate (ISO) Dimethoate O-analog 氧化乐果乳油 Thiophosphorsäure-O,O-dimethyl-S-(N-methylcarbamoyl)methylester 高渗氧乐果乳油 O,O-dimethyl S-(2-methylamino)-2-oxoethyl phosphorothioate 氧乐果 PHOSPHOROTHIOIC ACID, O
MDL NumberMFCD00055441
Beilstein Registry Number1785256
EC Number214-197-8
Chemical Name TranslationO,O-二甲基-S-(N-甲基氨基甲酰甲基)硫代磷酸酯
Wiswesser Line Notation1OPO&O1&S1VM1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {Chemicalbook} 农药: 杀虫（螨）剂: 有机磷杀虫剂
  • {SNA} Alphabetical Index of Analytical Standards, Method and Regulation Specific, Acaricides, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Baby Food Directives 13/2003 EC & 14/2003 EC, Chromatography, Environmental Standards, European Community: ISO, DIN and DL 152, Insecticides, N-P, O, Organophorous, Organophosphate, Pesticide Class, Pesticides & Metabolites, Pesticides Standards, Pesticides, toxic to bees
  • Sulfur & Selenium Compounds
  • Agro-Products
  • {uni_hamburg} no charge; amide; 1fragment
  • Phosphorylating and Phosphitylating Agents

产品应用

  • Insecticidal, acaricidal, and fungicidal combinations of carboxamides and other pesticides.

相关文献及参考

  • Dugo, G., et al.: Food Chem., 16, 435 (2005),
  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSTF8050000
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P310
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H300 Fatal if swallowed 吞食致命
WGK Germany3
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T,N T+;N,N,T+,T T+;N
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S1/2 None 上锁保管并避免儿童触及；
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R21 Harmful in contact with skin 与皮肤接触有害
Storage condition 储存温度2-8℃ 0-6°C
Packing GroupII
Hazard Class6.1(a)
UN Number 3018
Restrict {} 剧毒化学品 危险品
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C144,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 13 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 55 mg/kg
TOXIC EFFECTS :
   D

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C144,1991

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >1500 mg/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A304,1983

TYPE OF TEST

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 90 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 283,113,1992

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 6385 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,405,1975

其他信息

  • 灭火剂:砂土、干粉、泡沫
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 产品特性:内吸广谱性硫赶式一硫代磷酸酯类杀虫剂，又称作氧化乐果。对高等动物毒性较高，对皮肤有刺激性，对蜜蜂有毒。对害虫害螨具有很强的内吸作用，也有触杀作用。
  • 急救治疗:[1]用阿托品1～5mg皮下或静脉注射(按中毒轻重而定) [2]用解磷定0.4－1.2g 静脉注射(按中毒轻重而定) [3]禁用吗啡、茶硷、吩噻嗪、利血平。 [4]误服立即引吐、洗胃、导泻(清醒时才能引吐)。
  • 类别:农药
  • MOL 文件:1113-02-6.mol
  • 中毒症状:急性中毒多在12小时内发病，口服立即发病。轻度：头痛、头昏、恶心、呕吐、多汗、无力、胸闷、视力模糊、胃口不佳等，全血胆碱酯酶活力一般降 至正常值的70－50%。中度：除上述症状外还出现轻度呼吸困难、肌肉震颤 、瞳孔缩小、精神恍惚、行走不稳、大汗、流涎、腹疼、腹泻。重者还会出现昏迷、抽搐、呼吸困难、口吐白沫、大小便失禁，惊厥，呼吸麻痹。
  • 毒性:大鼠急性经口LD 50 为700mg/kg （7d)。工业品对大鼠急性经口LD 50 为30～60mg/kg，急性经皮LD 50 为700～1400mg/kg。鲤鱼LC 50 >500mg/L (96h)。对蜜蜂及瓢虫、食蚜蝇等有毒。
  • 方法一:后氨解法 二甲基硫代磷酸铵盐的制备 将亚磷酸二甲酯与硫黄悬浮剂在25～30℃通氨反应1.5～2h制得。 O，O-二甲基-S-（甲氧羰基甲基）硫代磷酸酯的制备 将氯乙酸甲酯与二甲基硫代磷酸铵盐反应制得，加少量催化剂（如NaI)，反应温度控制在55～60℃。 氧乐果的合成 O，O-二甲基-S-（甲基羰基甲基）硫代磷酸酯与一甲胺反应，温度-5～10℃，一甲胺过量，氯仿为溶剂。 先氨解法 异氰酸酯法
  • 外观性质:纯品为无色透明油状液体。工业品为黄色液体。
  • 注意事项:[1]啤酒花、菊科植物、高粱有些品种及烟草、枣树、桃、杏、梅树、橄榄无 花果、柑桔等作物，对稀释倍数在1500倍以下的氧乐果乳剂敏感,使用时要先做药害试验，才能确定使用
  • 上游原料:甲醇 --> 三氯甲烷 --> 氨 --> 苯 --> 硫磺 --> 三氯化磷 --> 一甲胺 --> 氯乙酸 --> 二甲基硫 --> 氯乙酸甲酯 --> 磷酸酯 --> 乳油 --> 亚磷酸二甲酯 --> 硫代磷酸铵盐 --> 乐果原油
  • {Chemica
  • 用途三:属高效、广谱性有机磷杀虫、杀螨剂，具有内吸、触杀、渗透和胃毒作用，可用于水稻、小麦、棉花和果树等作物
  • 用途四:本品为高效、高毒、广谱性杀虫、杀螨剂，具有较强的内吸、触杀和胃毒作用。用于防治棉蚜、棉叶蝉、稻飞虱、稻叶蝉、稻蓟马、橘蚜、红蜘蛛、柑橘粉虱、木虱、红蜡蚧等。 如防治稻叶蝉、稻飞虱、稻蓟马等，每百平方米用40%乳油7.5～11.3mL，对水7.5kg喷雾。防治棉花害虫每百平方米用40%乳油7.5mL,对水7.5～10.5kg喷雾。防治矢尖蚧、糠片蚧，在若蚧发生盛期，用40%乳油1000～2000倍液喷雾。
  • 可燃性危险特性:明火可燃; 受热放出有毒氧化磷、氧化氮、氧化硫气体
  • 方法二:可采用异氰酸酯法、先胺解法或后胺解法等。后胺解法是先用三氯化磷、甲醇制成亚磷酸二甲酯，再加入定量硫黄粉后通氨反应得到二甲基硫代磷酸铵，再与氯乙酸甲酯缩合成硫代磷酸酯。然后在低温下与一甲胺进行胺解反应生成氧化乐果原油。后胺解法得到的原油含氧化乐果70%以上，以三氯化磷计收率42%。市售的氧化乐果为40%乳油。原料消耗定额：三氯化磷710kg/t、甲醇490kg/t、氯乙酸甲酯（90%）690kg/t、一甲胺（40%）350kg/t、硫磺155kg/t、液氨110kg/t。
  • Sigma Aldrich:1113-02-6(sigmaaldrich)
  • 下游产品:菊·氧乳油
  • 用途:氧乐果主要用于防治刺吸式口器害虫和植食性螨类，杀虫谱及药效高于乐果。防治已对乐果及其他有机磷杀虫剂产生抗药性的蚜、螨有特效，也能防治卷叶蛾等咀嚼式口器害虫。氧乐果乳油对水常量喷雾，可防治谷

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. O - Alphabetic

相关产品推荐