2,2'-Dichlorodiethyl ether 二氯乙醚
CAS 111-44-4 MFCD00000975
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
- {uni_hamburg} no charge; ether; 1fragment
- Building Blocks, C2 to C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Short: III/20a
- Merck:14,3066 Beilstein:1(4)1375
- Merck:14,3066
- Short: III/38A
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H351 Suspected of causing cancer 怀疑致癌
- H330 Fatal if inhaled 吸入致命
- H310 Fatal in contact with skin 皮肤接触致命
- H300 Fatal if swallowed 吞食致命
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P310
- P301+P310+P330
- P302+P350
- P302+P352+P310+P361+P364
- P303+P361+P353
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P337+P313
- P308+P311
- P337+P313
- P403+P233
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
- R10 Flammable 易燃
- R11 Highly flammable 非常易燃
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 33 gm/kg/79W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Blood - lymphoma, including Hodgkin's disease REFERENCE : JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 42,1101,1969
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 2400 mg/kg/60W-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application REFERENCE : JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 48,1431,1972
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 209 mg/kg TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - ptosis Gastrointestinal - changes in structure or function of salivary glands Gastrointestinal - hypermotility, diarrhea REFERENCE : ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,163,1992
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 90 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2A,2518,1981
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 330 mg/m3/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GMAT "Toxicometric Parameters of Industrial Toxic Chemica
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 75 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 30,63,1948
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 1 mg/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 8(Suppl 7),1,1986
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 1457 mg/plate REFERENCE : DHEFDK HEW Publication (FDA. United States). (Washington, DC) ?-1979(?). For publisher information, see HPFSDS. Volume(issue)/page/year: FDA-78-1046,1978
TYPE OF TEST : Specific locus test ROUTE OF EXPOSURE : Parenteral TEST SYSTEM : Insect - Drosophila melanogaster DOSE/DURATION : 10500 ppm REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 23,51,1994
其他信息
- 刺激数据:皮肤- 兔子 500 毫克 轻度; 眼睛- 兔子 100 毫克 重度
- 外观性质:带有辣味和水果味的无色透明液体。
- 灭火剂:干粉、泡沫
- 检测方法:GC
- 不溶于水,和大多数有机溶剂混溶。
- 海关编码:29091900
- Alfa Aesar:双(2-氯乙基)醚,99% Bis(2-chloroethyl) ether, 99%(111-44-4)
- 爆炸物危险特性:与空气混合可爆
- 方法一:二氯乙醚(111-44-4)由氯乙醇经分子间脱水而制得。也是乙烯与次氯酸制氯乙醇时的副产品。
- Sigma Aldrich:111-44-4(sigmaaldrich)
- Acros Organics:二(2-氯乙基)醚 2,2-Dichlorodiethylether, 99+%(111-44-4)
- 二氯乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0472 双(2-氯乙基)醚 Bis(2-chloroethyl) Ether 25G 250元 2014/06/02 B0472 双(2-氯乙基)醚 Bis(2-chloroethyl) Ether 500G 484元 2010/06/21 264940050 二氯乙醚 2,2'-Dichlorodiethyl ether 99+% 5 ML 79元
- MOL 文件:111-44-4.mol
- 用途一:用作气相色谱固定液及脂肪、石蜡、油类等的溶剂和干洗剂
- 可燃性危险特性:可燃; 燃烧产生有毒氯化物气体
- 储运特性:库房通风低温干燥; 与食品原料分开储运
- 类别:农药
- 下游产品:N-甲基吗啡啉 --> 四氢吡喃-4-甲醛 --> 4-溴甲基四氢吡喃 --> 四氢吡喃-4-甲酸 --> 4-(2-氨乙基)四氢吡喃 --> 4-氨甲基四氢吡喃 --> 四氢吡喃-4-甲酰氯 --> (四氢-2H-吡喃-4-基)甲醇 --> 苄索氯铵 --> 2,2'-氧双(乙胺)盐酸盐 --> N-氨基吗啉 --> 地芬尼泰
- 用途二:用作橡胶、树脂等的溶剂
- 急性毒性:口服- 大鼠 LD50: 75 毫克/ 公斤; 口服- 小鼠 LD50: 209 毫克/ 公斤
- TCI Shanghai:二(2-氯乙基)醚 Bis(2-chloroethyl) Ether,>;99.0%(GC)(111-44-4)
- 职业标准:TWA 0.5 毫克/ 立方米; STEL 1.0 毫克/ 立方米
- 毒性分级:高毒
- 用途三:111-44-4(二氯乙醚)是合成N-甲基吗啉的原料药。同时也用作土壤熏蒸杀虫剂。
- MSDS 信息:二氯乙醚(111-44-4).msds
- 图谱信息:二氯乙醚(111-44-4)核磁图( 13 CNMR) 二氯乙醚(111-44-4)Raman光谱 二氯乙醚(111-44-4)质谱(MS) 二氯乙醚(111-44-4)核磁图( 1 HNMR) 二氯乙醚(111-44-4)红外图谱(IR1)
- 蒸气压:0.4 mm Hg ( 20 °C)