CAS 111-15-9 MFCD00009251-2-Ethoxyethyl acetate 乙酸-2-乙氧基乙酯 TAO{mole}

2-Ethoxyethyl acetate 乙酸-2-乙氧基乙酯

CAS 111-15-9 MFCD00009251

化学结构图

SMILES: CCOCCOC(C)=O

化学属性

Mol. Formula	C₆H₁₂O₃
Mol. Weight	132.16
Refractive index	1.4040 to 1.4070
Boiling Point	-
Density	0.975
Melting Point	No data available
Flash Point	-
TSCA	Yes
Autoignition Point	715 °F
Vapor Density	4.6 (vs air)
Vapor Pressure	2 mmHg ( 20 °C)
Solubility	微溶于水，可混溶于芳烃等多数有机溶剂。

别名和识别编码

Chemical Name	2-Ethoxyethyl acetate
Synonym	'& 1-乙酰氧基-2-乙醚 Cellosolve® 醋酸酯乙二醇单乙醚乙酸酯 2-ETHOXYETHANOL ACETATE 2-Ethoxyethyl Acetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	111-15-9
PubChem Substance ID	87569362
EC Number	203-839-2
Beilstein Registry Number	1748677
MDL Number	-
Reaxys-RN	1748677
Merck Number	3751
Chemical Name Translation	乙酸-2-乙氧基乙酯
Wiswesser Line Notation	2O2OV1
LabNetwork Molecule ID	LN00196318
Canonical SMILES	-

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分类

{SNA} Acids and Esters, Additional Standards, Analytical Standards, Certified Reference Materials (CRMs), E, Fluka CRMs for Chromatography (neats), Food and Cosmetic Component Standards, Organic CRMs Alphabetical, Organic CRMs TraceCERT, Organic Pollutant Standards, SVHC, Standards for Personal Care and Cosmetic Products, Volatile & Semivolatile Standards, prohibited substances (EU-REGULATION No 1223/2009), 分析/色谱
{uni_hamburg} no charge; ester; ether; 1fragment
{SNA} Acids and Esters, Analytical Standards, Analytical/Chromatography, Certified Reference Materials (CRMs), Chromatography, Fluka CRMs for Chromatography (neats), O
{SNA} Building Blocks,

产品应用

乙二醇乙醚醋酸酯(CAC)是性能优良的酯类溶剂。

安全信息

GHS Symbol

WGK Germany2

Hazard Codes 3 T

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
H302+H312+H332
H332 Harmful if inhaled 吸入有害
H312 Harmful in contact with skin 皮肤接触有害
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECS KK8225000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P303+P361+P353
P304+P340+P312
P305+P351+P338+P337+P313
P308+P313
P332+P313
P337+P313
P370+P378
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

UN Number 1172

Risk Statements

R10 Flammable 易燃
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R60 May impair fertility 可能降低生殖能力
R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；

Packing GroupIII

Hazard Class3

Storage condition 4°C Flammables area

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 53(10),78,1988

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 10500 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 1/13/1967

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 12100 mg/m3/8H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1950 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History un

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 100 ppm/6H
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 57,33,1984

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 50 ppm/6H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   UCRR** Union Carbide Research Report.  (Union Carbide Corp., Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 09OCT1984

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 70 gm/kg
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
   Reproductive - Specific Developmental Abnormalities - cardiovascular
   (circulatory) system
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-

其他信息

乙二醇乙醚醋酸酯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80062228 乙二醇乙醚乙酸酯 500ml 96.2元 2011/08/23 xp400244 乙二醇乙醚乙酸酯 5ml 45元 2011/04/16 E0049 乙酸2-乙氧基乙酯 2-Ethoxyethyl Acetate 25ML 139元
毒性分级:中毒
Acros Organics:2-乙氧基乙基乙酸酯 2-Ethoxyethyl acetate, 99%(111-15-9)
刺激数据:皮肤- 兔子 490 毫克轻度; 眼睛- 兔子 40 毫克中度
急性毒性:口服- 大鼠 LD50: 2700 毫克/ 公斤; 口服- 小鼠 LD50: 1910 毫克/ 公斤
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
图谱信息:乙二醇乙醚醋酸酯(111-15-9)红外图谱(IR1) 乙二醇乙醚醋酸酯(111-15-9)Raman光谱乙二醇乙醚醋酸酯(111-15-9)核磁图( 13 CNMR) 乙二醇乙醚醋酸酯(111-15-9)核磁图( 1 HNMR) 乙二醇乙醚醋酸酯(111-15-9)质谱(MS)
类别:易燃液体
TCI Shanghai:乙二醇乙醚醋酸酯 2-Ethoxyethyl Acetate,>;98.0%(GC)(111-15-9)
Sigma Aldrich:111-15-9(sigmaaldrich)
用途二:用作溶剂，与其他化合物配合用作皮革粘合剂、油漆剥离剂、金属热镀抗腐蚀涂料等。
MOL 文件:111-15-9.mol
用途四:乙二醇乙醚醋酸酯(CAC)是性能优良的酯类溶剂。
外观性质:无色液体，有微弱的类似芳香脂的气味。
MSDS 信息:乙酸乙二醇乙醚(111-15-9).msds
蒸气压:2 mm Hg ( 20 °C)
危险特性:3.3类高闪点易燃液体。
方法一:1.由乙二醇单乙醚与乙酐反应而得将乙酐和浓硫酸混合，加热到130℃后，慢慢滴加乙二醇单乙醚，反应温度维持在130-135℃，加完再加流1-2h，回流温度为140℃。冷却后用碳酸钠中和至pH=7-8，再以工业无水碳酸钾干燥。滤出干燥剂进行粗分馏，收集150-160℃间的馏出物。再分馏，收集155.5-156.5℃的馏分即为成品。也可由乙二醇单乙醚与乙酸以浓硫酸催化，在苯中回流反应而得。乙二醇单乙醚在阳离子树脂催化下与乙酸反应，不断去掉生成的水，然后蒸馏得成品，此法乙酸转化率为94.5%，产品的选择性为98.5%。2.2-乙氧基乙酸与乙醇反应法。3.醋酸乙酯与乙氧基乙醇酯交换法。4.醋酸与乙氧基乙醇反应法。5.环氧乙烷和醋酸乙酯反应法。
蒸气密度:4.6 (vs air)
储运特性:库房通风低温干燥; 与氧化剂分开存放
上游原料:乙酸乙酯 --> 乙酸 --> 碳酸钾 --> 乙二醇乙醚 --> 干燥剂 --> 阳离子树脂 --> 2-乙氧基乙酸
用途三:乙二醇醚醋酸酯(111-15-9)是具有多官能团的非公害溶剂。乙二醇醚醋酸酯(111-15-9)是涂料行业一种为了提高涂膜性能而不可缺少的辅助溶剂，广泛应用于轿车漆、电视机漆、冰箱漆、飞机漆等高档油漆中。还可用作保护性涂料、染料、树脂、皮革、油墨的溶剂，也可用于金属、玻璃等表面清洗剂的配方中，另可用作化学试剂。
Alfa Aesar:2-乙氧基乙基乙酸酯,98+% 2-Ethoxyethyl acetate, 98+%(111-15-9)
职业标准:TWA 27 毫克/ 立方米; STEL 50 毫克/ 立方米
可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生刺激烟雾
用途一:用作树脂、皮革、油墨等的溶剂