(S)-Alpha,Alpha-Diphenylmethylprolinol α,α-二苯基-N-甲基-L-脯氨醇
CAS 110529-22-1 MFCD00145245
化学结构图
SMILES: CN1CCC[C@H]1C(O)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C18H21NO |
|---|---|
| Mol. Weight | 267.37 |
| Melting Point | 66-72 |
| TSCA | No |
| Appearance | white to pale-yellow pwdr. |
别名和识别编码
| Chemical Name | (S)-Alpha,Alpha-Diphenylmethylprolinol |
|---|---|
| MDL Number | MFCD00145245 |
| Synonym | (S)-,-Diphenyl-N-methyl-2-pyrrolidinemethanol (S)-α,α-Diphenyl-N-methyl-2-pyrrolidinemethanol (S)-α,α-二苯基-N-甲基-2-吡咯烷甲醇 α,α-二苯基-N-甲基-L-脯氨醇 (S)-α,α-二苯基-N-甲基-2-吡咯烷甲醇 |
| CAS Number | 110529-22-1 |
| Beilstein Registry Number | 4749387 |
| PubChem Substance ID | 87571133 |
| Chemical Name Translation | α,α-二苯基-N-甲基-L-脯氨醇 |
| Reaxys-RN | 1535407 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Proline-Based Organocatalysts
产品应用
- 二烷基锌不对称加成到羰基化合物的反应所用配体
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
