Ethylene glycol monoethyl ether 超干乙二醇单乙醚

CAS 110-80-5 MFCD00002869

化学结构图

110-80-5
SMILES: CCOCCO

化学属性

Mol. FormulaC4H10O2
Mol. Weight90.12
Density0.93
Autoignition Point460 °F
Refractive index1.4060 to 1.4090
Vapor Density3.1 (vs air)
Boiling Point135°C
Vapor Pressure3.8 mmHg ( 20 °C)
Melting Point-90
Flash Point42°C
TSCAYes
Solubility与水混溶,可混溶于醇等多数有机溶剂。
Stability对湿度敏感

别名和识别编码

Chemical NameEthylene glycol monoethyl ether
MDL NumberMFCD00002869
CAS Number110-80-5
EC Number203-804-1
Beilstein Registry Number1,467
Synonym 2-Ethoxyethanol 2-ee 2-ethoxy-ethano 2-ethoxyethanol(ethyleneglycolmonoethyl 2-乙氧乙醇 2-乙氧基乙醇 2-乙氧基乙醇(乙二醇单乙醚) CELLOSOLVE CELLOSOLVE SOLVENT CELLOSOLVE(R) Dowanol 8 Dowanol EE ETHYL CELLOSOLVE ETHYL GLYCOL Ektasolve EE Ethyl cellosolve Ethylene glycol monoethyl ether Ethylene glycol-monoethyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {hazard_com} RCRA waste number U359
PubChem Substance ID8076
Merck Number3750
Chemical Name Translation超干乙二醇单乙醚
Reaxys-RN1098271
InChIKeyZNQVEEAIQZEUHB-UHFFFAOYSA-N
Wiswesser Line NotationQ2O2
LabNetwork Molecule IDLN00195063
InChIInChI=1S/C4H10O2/c1-2-6-4-3-5/h5H,2-4H2,1H3
Canonical SMILESCCOCCO
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分类

  • {SA} Alcohols, Aliphatic, Allergens, Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Application, Chemical Class, Chromatography, Cosmetic Standards, Cosmetics, E, E-L, EQ - EZ, Environmental Standards, Other Additives, Other Allergens, Solvents, Volatiles/ Semivolatiles
  • {SNA} Alcohols,
  • {SNA} Amber Glass Bottles, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents, Spectrophotometric Grade,
  • {SNA} ReagentPlus,
  • {SNA} ReagentPlus,

产品应用

  • 该品为低挥发性溶剂。本品主要用于硝基纤维素漆和飞机翼涂料的溶剂,还可用作清漆的涂膜剂,净化液、染料浴、水溶性颜料和染料溶液,精炼皮革的溶剂,并能增加乳胶的稳定性。

相关文献及参考

  • Merck:14,3750 Beilstein:1,467
  • Merck:14,3750

安全信息

Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R60 May impair fertility 可能降低生殖能力
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R10 Flammable 易燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P337+P313
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P308+P313
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P312
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338+P337+P313
  • P308+P311
  • P241+P242+P243
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P403+P235
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302 Harmful if swallowed 吞食有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKK8050000
Packing GroupIII
UN Number 1171
Hazard Codes T
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class3
Warnings 危化品目录(2015)
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2000 ppm/7H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. (National
   Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair
   Memorial Laboratory, Lehigh Univ., Bethlehem, PA 18015)
   Volume(issue)/page/year: 1,54,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1707 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - chronic pulmonary edema
   Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
   acute tubular necrosis)
   Blood - changes in spleen
REFERENCE :
   FEPRA7 Federation Proceedings, Federation of American Societies for
   Experimental Biology. (Bethesda, MD)  V.1-46, 1942-87.
   Volume(issue)/page/year: 6,342,1947

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1820 ppm/7H
TOXIC EFFECTS :
   Behavioral - analgesia
   Lungs, Thorax, or Respiration - dyspnea
   Kidney, Ureter, Bladder - hematuria
REFERENCE :
   JIHTAB Journal of Industrial Hygiene a

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 4,180,1984

TYPE OF TEST            : Sperm Morphology
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 23400 mg/kg/5W (Intermittent)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   84,576,1986

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 3170 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 6830 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1800 mg/kg
SEX/DURATION            : female 7-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 4,87,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 600 mg/kg
SEX/DURATION            : female 10-12 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
   Reproductive - Specific Developmental Abnormalities - cardiovascular
   (circulatory) system
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 4,87,1984

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 10 ppm/6H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Off

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 mg/kg
SEX/DURATION            : male 5 day(s) pre-mating
TOXIC EFFECTS :

Restrict 危险品

其他信息

  • 上游原料:乙醇 --> 甲
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运
  • 毒性分级:中毒
  • 用途二:用作硝基赛璐珞、假漆等的溶剂,皮革着色剂及乳化液稳定剂
  • 下游产品:双苯酰草胺 --> 溶剂黄 21 --> 1-(2-乙氧基乙基)哌嗪 --> 乙二醇乙醚醋酸酯 --> [2,4-二氢-4-[(2-羟基-5-硝基苯基)偶氮]-5-甲基-2-苯基-3H-吡唑-3-氧根合(2-)][1-[(2-羟基-4-硝基苯基)偶氮]-2-萘酚根合(2-)]钴酸(1-)钠 --> C.I.酸性蓝209 --> 溶剂黑 34 --> 酸性橙 --> 2-溴乙基乙基醚 --> 荧光增白剂 CA,荧光增白剂 AD,荧光增白剂 DCR,1-(4'-甲磺酸)-苯基-3-对氯苯基吡唑啉 --> 皮革喷涂黑RL
  • MSDS 信息:乙二醇乙醚(110-80-5).msds
  • 乙二醇乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80062118 乙二醇乙醚 500ml 26.4元 2011/08/23
  • 图谱信息:乙二醇乙醚(110-80-5)红外图谱(IR2) 乙二醇乙醚(110-80-5)红外图谱(IR1) 乙二醇乙醚(110-80-5)质谱(MS) 乙二醇乙醚(110-80-5)Raman光谱 乙二醇乙醚(110-80-5)核磁图( 1 HNMR) 乙二醇
  • 爆炸物危险特性:蒸气与空气混合可爆
  • 凝固点:-70℃
  • Sigma Aldrich:110-80-5(sigmaaldrich)
  • 职业标准:TLV-TWA 19 毫克/立方米; STEL 40 毫克/立方米
  • 蒸气密度:3.1 (vs air)
  • 类别:易燃液体
  • 参考质量标准:酸度(As HAc) % ≤0.01 水份 % ≤0.1 色度 Pt-Co ≤20 沸程 132~138℃
  • 可燃性危险特性:易燃; 火场释放辛辣刺激烟雾
  • MOL 文件:110-80-5.mol
  • Acros Organics:2-乙氧基乙醇(乙二醇单乙
  • 几乎无气味无臭,能与水;乙醇;乙醚;丙酮和酯类混溶。能溶解多种油类;树脂及蜡等。
  • TCI Shanghai
  • 用途四:乙二醇单乙醚(110-80-5)主要用于硝基纤维素漆和飞机翼涂料的溶剂,还可用作清漆的涂膜剂,净化液、染料浴、水溶性颜料和染料溶液,精炼皮革的溶剂,并能增加乳胶的稳定性。
  • 刺激数据:皮肤-兔子 500 毫克 轻度; 眼睛-兔子 50 毫克 中度
  • 灭火剂:干粉, 二氧化碳, 雾状水, 泡沫
  • Alfa Aesar:2-乙氧基乙醇,99% 2-Ethoxyethanol, 99%(110-80-5)
  • 用途五:该品为低挥发性溶剂。本品主要用于硝基纤维素漆和飞机翼涂料的溶剂,还可用作清漆的涂膜剂,净化液、染料浴、水溶性颜料和染料溶液,精炼皮革的溶剂,并能增加乳胶的稳定性。
  • 急性毒性:口服-大鼠 LD50: 2125 毫克/公斤; 口服-小鼠 LD50: 2451 毫克/公斤
  • 用途一:用作溶剂、抽提剂、防水剂及有机中间体
  • 外观性质:无色液体,几乎无气味。
  • 用途三:该品为低挥发性溶剂。用作硝基赛璐珞、假漆、天然和合成树脂等的溶剂,还可用于皮革着色剂、乳化液稳定剂、油漆稀释剂、脱漆剂和纺织纤维的染色剂等。另外,还是生产乙酸酯的中间体。
  • 方法一:由环氧乙烷与乙醇反应而得。在25-30℃,将环氧乙烷缓加入无水乙醇中,待温度升至70℃,反应完后放置过夜。回收乙醇,用10%氢氧化钠溶液中和至pH=8,分
  • 危险性类别:第3.3类高闪点易燃液体
  • 蒸气压:3.8 mm Hg ( 20 °C)

系列性分类


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