(R)-(-)-N-Boc-3-pyrrolidinol N-叔丁氧羰基-(R)-3-吡咯烷醇
CAS 109431-87-0 MFCD01317838
化学结构图
SMILES: CC(C)(C)OC(=O)N1CC[C@H](O)C1
化学属性
| Mol. Formula | C9H17NO3 |
|---|---|
| Mol. Weight | 187.24 |
| Melting Point | 62-65°C |
| TSCA | No |
| pH | :A |
| Boiling Point | 273.3±33.0 °C at 760 mmHg |
别名和识别编码
| Chemical Name | (R)-(-)-N-Boc-3-pyrrolidinol |
|---|---|
| CAS Number | 109431-87-0 |
| Alfabeta Name | HYDROXYPYRROLIDINECARBOXYLICACIDTERTBUTYLESTER R31()------ |
| MDL Number | MFCD01317838 |
| Synonym | (R)-(-)-N-Boc-3-pyrrolidinol {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(-)-N-Boc-3-pyrrolidinol {} {} {} {} {} {} {} {} {} {} {} {} {} {} { |
| PubChem Substance ID | 87559627 |
| Chemical Name Translation | N-叔丁氧羰基-(R)-3-吡咯烷醇 |
| Reaxys-RN | 4670167 |
| LabNetwork Molecule ID | LN00005080 |
| Canonical SMILES | O[C@@H]1CCN(C1)C(=O)OC(C)(C)C |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines
- {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines
相关文献及参考
- 1. Lee, J. et al Bioorg. Med. Chem. Lett. 10 , 1063, (2000) 摘要
- Bioorg. Med. Chem. 12 , 2099-2114, (2004) 摘要
安全信息
GHS Symbol
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P301+P312+P330
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P302+P350
- P337+P313
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P312+P362+P364
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P304+P340+P312
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P305+P351+P338+P337+P313
- H302+H312+H332
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R50/53
