1,3-Dimercaptopropane 1,3-丙二硫醇
CAS 109-80-8 MFCD00004904
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专业采购外包团队在线服务
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分类
- {Chemicalbook} 食品添加剂: 食用香料(增香剂): 天然等同香料和人造香
- {SNA} A-D, Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O - Z, O-P
- Building Blocks, Chemical Synthesis, Dithiols, Materials Science, Micro/Nano
- {SNA} A-D, Alphabetical Listings, Certified Food Grade Products, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, N-P, O - Z, O-P
- {SNA} Building Blocks, Chemical Synthesis, Dithiols, Micro/NanoElectronics, Organic Building Blocks,
相关文献及参考
- Alternatively, 1,3-dithianes can be prepared by alkylation with reactive gem-dihalides under phase-transfer conditions: Liebigs Ann. Chem., 1589 (1982).
- For deprotection methods and uses of 1,3-dithianes as acyl anion equivalents, see: 1,3-Dithiane, A10505.
- Merck:14,7801
- Merck:14,7801 Beilstein:1,476
- Precursor of cyclic dithioacetal (1,3-dithiane) derivatives of carbonyl compounds. The protection step is catalyzed by Lewis acids, e.g. BF3 etherate: Tetrahedron Lett., 871 (1971), TiCl4: Tetrahedron Lett., 24, 1289 (1983), Aluminum trifluoromethanesulfonate, B20785, or Indium(III) trifluoromethanesulfonate, 40131. Diothioacetalization can be accomplished under neutral, solvent-free conditions using Lithium trifluoromethanesulfonate, 39322, as catalyst: Tetrahedron Lett., 40, 4055 (1999). For the preparation of monocyclic dithioacetals of ß-diketones at low temperature in the presence of BF3 etherate, see: Tetrahedron, 44, 2283 (1988).
- Short: III/38B
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H227 Combustible liquid 可燃液体
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P332+P313
- P370+P378
- P305+P351+P338+P337+P313
- P301+P312+P330
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P302+P350
- P337+P313
- P302+P352+P332+P313+P362+P364
- P403+P235
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1070 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 14,111,1985
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Mammal - cat DOSE/DURATION : 28 mg/kg TOXIC EFFECTS : Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Gastrointestinal - changes in structure or function of salivary glands REFERENCE : JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 87(Suppl),6,1946
其他信息
- 微溶于水,和乙醇、乙醚和氯仿混溶。
- 蒸气密度:>;1 (vs air)
- 蒸气压:5 mm Hg ( 37.7 °C)
- Alfa Aesar:1,3-丙二硫醇,97% 1,3-Propanedithiol, 97%(109-80-8)
- 检测方法:GC,NMR
- 下游产品:西司他丁 --> 2-甲基-1,3-二噻烷
- 图谱信息:1,3-丙二硫醇(109-80-8)红外图谱(IR1)
- 海关编码:29309070
- 用途一:用作日用香精
- 使用限量:FEMA:焙烤制品、肉制品、汤品、小吃食品、调味汁、糖果、糖霜,均0.2mg/kg。
- 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) 1,3-丙二硫醇 食品 食品用香料 用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
- F:13
- MSDS 信息:1,3-Dimercaptopropane(109-80-8).msds
- TCI Shanghai:1,3-丙二硫醇 1,3-Propanedithiol,>;95.0%(T)(109-80-8)
- 1,3-Propanedithiol is used for the protection of aldehydes and ketones via their reversible formation of dithianes. It is a dithiol used in self-assembled monolayers (SAMs).
- 参考质量标准:FAO/WHO,1999 含量(GT-10-4) ≥98% 折射率(n D 20 ) 1.537~1.539 相对密度(d 4 20 ) 1.077~1.078
- Acros Organics:1,3-丙二硫醇 1,3-Propanedithiol, 98%(109-80-8)
- FEMA:3588
- 1,3-丙二硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0763 1,3-丙二硫醇 1,3-Propanedithiol 25ML 448元 2010/06/21 131412500 1,3-丙二硫醇 1,3-Propanedithiol 98% 250 ML 3397元 2010/06/21 131410500 1,3-丙二硫醇 1,3-Propanedithiol 98% 50 ML 995元
- Sigma Aldrich:109-80-8(sigmaaldrich)
- 1,3-丙二硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 P0763 1,3-丙二硫醇 1,3-Propanedithiol 25ML 603元 2010/06/21 131412500 1,3-丙二硫醇 1,3-Propanedithiol 98% 250 ML 3397元 2010/06/21 131410500 1,3-丙二硫醇 1,3-Propanedithiol 98% 50 ML 995元
- MOL 文件:109-80-8.mol
- 毒性:GRAS(FEMA)。