(S)-(-)-3-Boc-4-Methoxycarbonyl-2,2-Dimethyl-1,3-Oxazolidine (S)-(-)-3-(叔丁氧羰基)-4-甲氧羰基-2,2-二甲基-1,3-噁唑烷

CAS 108149-60-6 MFCD00192279

化学结构图

108149-60-6
SMILES: CC(C)(C)OC(=O)N1[C@@H](COC1(C)C)C(=O)OC

化学属性

Mol. FormulaC12H21NO5
Mol. Weight259
Refractive index1.4410 to 1.4450
Boiling Point101-102
Density1.082
Flash Point93°C(lit.)

别名和识别编码

Chemical Name(S)-(-)-3-Boc-4-Methoxycarbonyl-2,2-Dimethyl-1,3-Oxazolidine
Synonym
PubChem Substance ID87564650
MDL NumberMFCD00192279
CAS Number108149-60-6
Reaxys-RN3553624
Chemical Name Translation(S)-(-)-3-(叔丁氧羰基)-4-甲氧羰基-2,2-二甲基-1,3-噁唑烷
Beilstein Registry Number3553624
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Auxiliaries, Oxazolidinone Derivatives

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P403+P235
Signal word
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;

系列性分类


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