(3aS)-8,8-dimethyl-4,5,6,7-tetrahydro-3H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide (3aR,6S)-8,8-二甲基-4,5,6,7-四氢-3H-3a,6-亚甲基苯并[c]异噻唑2,2-二氧化物

CAS 107869-45-4 MFCD00013315

化学结构图

107869-45-4
SMILES: CC1(C)C2CC3=NS(=O)(=O)C[C@@]13CC2

化学属性

Mol. FormulaC10H15NO2S
Mol. Weight213.30
Melting Point228-230 °C(lit.)

别名和识别编码

Chemical Name(3aS)-8,8-dimethyl-4,5,6,7-tetrahydro-3H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide
CAS Number107869-45-4
Synonym (1S)-(-)-10,10-二甲基-3-硫杂-4-氮杂三环[5.2.1.01,5]癸-4-烯-3,3-二氧化物 (3aS)-(-)-4,5,6,7-四氢-8,8-二甲基-3H-3a,6-亚甲基-2,1-苯并异噻唑基-2,2-二氧化物 (1S)-(-)-樟脑内磺酰亚胺 (3aS,6R)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-Dioxide
MDL NumberMFCD00064576
PubChem Substance ID87566402
Beilstein Registry Number85296
Chemical Name Translation(3aR,6S)-8,8-二甲基-4,5,6,7-四氢-3H-3a,6-亚甲基苯并[c]异噻唑2,2-二氧化物
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Sulfonimides/Sulfinimides
  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Sulfonimides/Sulfinimides
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Sulfonimides/Sulfinimides

产品应用

  • A useful synthetic intermediate. Used for asymmetric hydroxylation.

相关文献及参考

  • Beil. 27 ,IV,1019
  • Fieser 15 ,68
  • FT-IR 2 (1), 1530:D / FT-NMR 1 (1), 1455:B / RegBook 1 (1), 1077:L / Structure Index 1 , 167:D:6

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Sulfonimides/Sulfinimides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Sulfonimides/Sulfinimides - Organic Building Blocks
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Terpenes

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