Bismuththiol 2,5-二巯基噻二唑

CAS 1072-71-5 MFCD00003103

化学结构图

1072-71-5
SMILES: S=c1[nH][nH]c(=S)s1

化学属性

Mol. FormulaC2H2N2S3
Mol. Weight150.24568
Melting Point162 °C
Density1.8
TSCAYes
Solubility20 G/L (20 ºC)
Stability对光敏感
Appearance 黄色针状结晶。熔点173℃(分解),易溶于醚及碱溶液,微溶于醇,不溶于水、氯仿和苯。该品碱性溶液不稳定,久置析出硫。在空气中和遇光均不稳定。要在避光并充氮的瓶中保存。
Boiling Point211.3±23.0 °C at 760 mmHg

别名和识别编码

Chemical NameBismuththiol
CAS Number1072-71-5
Alfabeta NameTHIADIAZOLEDITHIOL 13425---,,,
MDL NumberMFCD00003103
Synonym 1,3,4-Thiadiazole-2,5-dithiol {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3,4-Thiadiazole-2,5-dithiol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87567268
EC Number214-014-1
Beilstein Registry Number113444
Reaxys-RN607013
Chemical Name Translation2,5-二巯基噻二唑
Wiswesser Line NotationT5NN DSJ CSH ESH
LabNetwork Molecule IDLN00141248
InChIInChI=1S/C2H2N2S3/c5-1-3-4-2(6)7-1/h(H,3,5)(H,4,6)
Canonical SMILESSC1=NN=C(S)S1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Thiadiazoles
  • Analytical Reagents, Analytical/Chromatography, Indicators, Metal Titration Indicators, Spectroscopy, Titration, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy

产品应用

  • 测定铋、铜、铅、钯和锑。光度测定铋和钯。铋的容量测定。

相关文献及参考

  • Reagent for bismuth.
  • Beilstein: 27,IV,7725

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany2
Hazard Codes 9
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSXI3850000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P310
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro
Packing GroupIII
UN Number 3335
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : >316 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   6,149,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

其他信息

  • TCI Shanghai:2.5- 二疏基噻二唑 Bismuthiol,>;95.0%(T)(1072-71-5)
  • 用途二:该品为分析试剂,与铋反应呈红色,与铜呈褐色,与铅生成鲜黄色沉淀。用于比色测定铋,光度测定锑和钯。
  • MOL 文件:1072-71-5.mol
  • 方法一:由肼与二硫化碳反应而得。
  • Acros Organics:2,5-二巯基-1,3,4噻二唑 2,5-Dimercapto-1,3,4-thiadiazole, 98%(1072-71-5)
  • 图谱信息:2,5-二巯基噻二唑(1072-71-5)质谱(MS) 2,5-二巯基噻二唑(1072-71-5)Raman光谱 2,5-二巯基噻二唑(1072-71-5)红外图谱(IR2) 2,5-二巯基噻二唑(1072-71-5)核磁图( 13 CNMR) 2,5-二巯基噻二唑(1072-71-5)红外图谱(IR1)
  • 用途一:用作医药中间体、有机合成原料、分析试剂、燃料添加剂等
  • Sigma Aldrich:1072-71-5(sigmaaldrich)
  • Hazard Note:Irritant
  • F:9-13
  • 易溶于乙醚和碱溶液,微溶于乙醇,不溶于水、氯仿和苯。碱性溶液不稳定,久置有硫析出。有刺激性。
  • MSDS 信息:DMTD(1072-71-5).msds
  • 2,5-二巯基噻二唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0593 试铋硫醇 Bismuthiol 25G 185元 2014/06/02 B0593 试铋硫醇 Bismuthiol 500G 1350元 2014/06/02 D0622 试铋硫醇[用于铅和铋的测定] Bismuthiol [for Determination of Lead and Bismuth] 25G 240元
  • 用途三:检定铋、铜、铅、钯和锑。光度测定铋和钯。铋的容量测定。
  • Alfa Aesar:2,5-二硫基-1,3,4-噻二唑,98+% 2,5-Dimercapto-1,3,4-thiadiazole, 98+%(1072-71-5)
  • 海关编码:29349990

系列性分类


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