CAS 106-41-2 MFCD00002313-4-Bromophenol 4-溴苯酚 TAO{mole}

4-Bromophenol 4-溴苯酚

CAS 106-41-2 MFCD00002313

化学结构图

SMILES: Oc1ccc(Br)cc1

化学属性

Mol. Formula	C6H5BrO
Mol. Weight	173
Boiling Point	235-236
Melting Point	61-64
Density	1.84
Flash Point	>110°(230°F)
TSCA	Yes
Solubility	微溶于水，溶于乙醇、乙醚、氯仿等。
Stability	对光敏感

别名和识别编码

Chemical Name	4-Bromophenol
CAS Number	106-41-2
EC Number	203-394-4
Beilstein Registry Number	1680024
MDL Number	MFCD00002313
PubChem Substance ID	7808
Reaxys-RN	1680024
Merck Number	1428
Synonym	Phenol, p-bromo- p-bromo-pheno 1-Bromo-4-hydroxybenzene 4-溴苯酚 4-bromo-pheno 4-Bromphenol 对溴酚,4-溴酚 p-bromohydroxybenzene AKOS BBS-00004402 4-bromo-phenol phenol, 4-bromo- 4-Bromophenoles para-bromophenol Parabromophenol p-Bromophenol 4-Bromophenol BROMOPHENOL-4 4-BROMOHYDROXYBENZENE p-Bromohydroxybenzene 对溴酚 Para Bromo Phenol 4-Bromophenol 4-BROMOPHENOL 1,4-bromophenol 4-BROMOPHENOL, 1000MG, NEAT Phenol, 4-bromo- p-Bromophenol p-Bromophenic acid 4-溴酚 4-Bromophenol p-Bromophenol p-bromophenol p-bromophenic acid p-bromophenicacid p-bromohydroxybenzene Phenol,4-bromo- p-Bromphenol 对溴苯酚 4-Bromophbenol p-Bromophenoles 4-溴苯酚，对溴酚 Phenol, p-bromo- 溴酚 P-BROMOPHENOL 4-Hydroxybrombenzol
Alfabeta Name	BROMOPHENOL 4-
Chemical Name Translation	4-溴苯酚
Wiswesser Line Notation	QR DE
LabNetwork Molecule ID	LN00192998
InChI	InChI=1S/C6H5BrO/c7-5-1-3-6(8)4-2-5/h1-4,8H

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产品应用

用于有机合成及制药工业，也用作杀虫剂

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xn Xn,Xi

RTECSSJ7960000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P305+P351+P338+P337+P313
P332+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；

Risk Statements

R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

UN Number UN2811 3077 2811

Packing GroupIII

Warnings 危化品目录(2015) IRRITANT

Storage condition 密封阴凉干燥避光保存。

Hazard Class9

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7200 mg/kg/18W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   19,413,1959

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 523 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 44(12),19,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 411 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 44(12),19,1979

Restrict 危险品

其他信息

用途一:用于制药工业及有机合成，也用作杀虫剂
图谱信息:4-溴苯酚(106-41-2)质谱(MS) 4-溴苯酚(106-41-2)核磁图( 13 CNMR) 4-溴苯酚(106-41-2)核磁图( 1 HNMR) 4-溴苯酚(106-41-2)红外图谱(IR1)
用途三:用于有机合成、医药、农药中间体。
Hazard Note:Irritant
下游产品:1-苯并呋喃-5-甲醛 --> 苯并呋喃-5-硼酸 --> 5-溴-2-苯并恶唑酮 --> 2-氨基-4-溴苯酚 --> 6-溴-2H-1,4-苯并噁嗪-3(4H)-酮 --> 1-苯并呋喃-5-甲腈 --> 6-溴-3,4-二氢-4-羟基-2H-苯并吡喃 --> 5-溴苯并呋喃 --> 1-(2-(4-溴苯氧基)乙基)吡咯烷 --> 4-溴苯甲醚 --> 4-苄氧基苯硼酸 --> 4-异丁氧基苯基硼酸 --> 4-溴-2-硝基苯酚 --> 4-溴-2-氯苯酚 --> 6-溴-4-二氢色原酮 --> 4-羟基苯硼酸 --> 枸橼酸他莫昔芬 --> 硫代氯磷酸二对溴苯酯
用途二:用作医药、农药、阻燃剂中间体
类别:有毒物品
方法一:由苯酚溴化而得。将溴素、二硫化碳溶液加入苯酚二硫化碳溶液中，在5℃以下开始加入，在搅拌下2h加完。苯酚和溴素接近等摩尔配料。将反应物蒸馏除去二硫化碳，再进行减压分馏，收集145-150℃（3.32-3.99kPa）馏分即得产品。产率80-84%。
Acros Organics:4-Bromophenol, 99%(106-41-2)
MSDS 信息:4-溴苯酚(106-41-2).msds
急性毒性:口服-小鼠LD50: 523 毫克/公斤; 腹腔-小鼠 LD50: 411 毫克/公斤
上游原料:溴 --> 二硫化碳
存储注意事项:惰性气体保护;光敏感
外观性质:无色或灰白色结晶。
易溶于乙醇、氯仿、乙醚和冰乙酸，溶于约7份水。加入微量水可使熔点大为降低，并阻止结晶。半数致死量(小鼠，经口)523mg/kg。对眼睛和皮肤有刺激性。
4-溴苯酚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B0787 4-溴苯酚 4-Bromophenol 25G 100元 2014/06/02 B0787 4-溴苯酚 4-Bromophenol 500G 960元 2010/06/21 304410050 4-溴苯酚 4-Bromophenol 97% 5 GR 259元
TCI Shanghai:4-溴苯酚 4-Bromophenol,>;98.0%(GC)(106-41-2)
储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
F:8-10-23
Alfa Aesar:4-溴苯酚,99% 4-Bromophenol, 99%(106-41-2)
用途四:用于有机合成及制药工业，也用作杀虫剂
可燃性危险特性:遇明火可燃; 燃烧释放有毒溴化物烟雾
灭火剂:二氧化碳、泡沫、砂土、雾状水。
毒性分级:高毒
MOL 文件:106-41-2.mol
职业标准:STEL 0.3 毫克/立方米
Sigma Aldrich:106-41-2(sigmaaldrich)