(1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN (1S,9S)-1,9-双[(叔丁基二甲基甲硅烷氧基)甲基]-5-氰基半咕啉
CAS 105251-52-3 MFCD00142698
化学结构图
SMILES: C[Si](C)(OC[C@@H]1CC/C(/N1)=C(\C#N)/C1CC[C@@H](CO[Si](C)(C)C(C)(C)C)N=1)C(C)(C)C
化学属性
| Mol. Formula | C24H45N3O2Si2 |
|---|---|
| Mol. Weight | 463.80 |
| Melting Point | 74-77 °C |
别名和识别编码
| Chemical Name | (1S,9S)-1,9-Bis[(tert-butyldimethylsiloxy)methyl]-5-cyanosemicorrin >=97.0% |
|---|---|
| Synonym | 半咕啉手性配体 2 (1S,9S)-1,9-双[(叔丁基二甲基甲硅烷氧基)甲基]-5-氰基半咕啉 |
| MDL Number | MFCD00142698 |
| PubChem Substance ID | 57647178 |
| Beilstein Registry Number | 5153664 |
| CAS Number | 105251-52-3 |
| Chemical Name Translation | (1S,9S)-1,9-双[(叔丁基二甲基甲硅烷氧基)甲基]-5-氰基半咕啉 |
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分类
- Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
- {SNA} Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
相关文献及参考
- 1. H. Fritschi et al. Helv. Chim. Acta 71 , 1553, (1988)
- 2. U. Leutenegger et al. Angew. Chem. 101 , 61, (1989)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
