CAS 10293-06-8 MFCD00003744-(1R,3S,4S)-3-bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one (1R,3S,4S)-3-溴-1,7,7-三甲基双环[2.2.1]庚烷-2-酮 TAO{mole}

(1R,3S,4S)-3-bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one (1R,3S,4S)-3-溴-1,7,7-三甲基双环[2.2.1]庚烷-2-酮

CAS 10293-06-8 MFCD00003744

化学结构图

SMILES: CC1(C)[C@@H]2CC[C@@]1(C)C(=O)[C@H]2Br

化学属性

Mol. Formula	C10H15BrO
Mol. Weight	231
Melting Point	75.0 to 77.0 deg-C
Boiling Point	274 ºC
Density	1.422

别名和识别编码

Chemical Name	(1R,3S,4S)-3-bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
Synonym	Camphor, 3-alpha-bromo-, (+)- Camphor, 3-bromo-, d- Bicyclo(2.2.1)heptan-2-one, 3-bromo-1,7,7-trimethyl-, (1R-endo)- (+)-3-Bromocamphor endo-3-Bromo-D-camphor; (1R-endo)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one (+)-3-溴樟脑 (1R,3S,4S)-(+)-3-Bromo-2-bornanone 内型-(1R)-3-溴-1,7,7-三甲基二环[2.2.1]庚烷-2-酮
MDL Number	MFCD00003744
Beilstein Registry Number	7(2)101
EC Number	233-652-1
CAS Number	10293-06-8
PubChem Substance ID	87563585
Reaxys-RN	3197237
Merck Number	1414
Chemical Name Translation	(1R,3S,4S)-3-溴-1,7,7-三甲基双环[2.2.1]庚烷-2-酮

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安全信息

GHS Symbol

WGK Germany3

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352+P332+P313+P362+P364
P305+P351+P338
P305+P351+P338+P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

RTECSED6750000

Signal word

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xi

Safety Statements

S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S36 Wear suitable protective clothing 穿戴适当的防护服；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,20,1953