Zirconium tetrachloride 氯化锆
CAS 10026-11-6 MFCD00011306
化学结构图
SMILES: Cl[Zr](Cl)(Cl)Cl
化学属性
| Mol. Formula | ZrCl4 |
|---|---|
| Mol. Weight | 233.04 |
| Density | 2.8 g/mL at 25 °C(lit.) |
| TSCA | Yes |
| Melting Point | 437°C |
| Solubility | 溶于冷水、乙醇、乙醚，不溶于苯、四氯化碳、二硫化碳。 |
| Vapor Pressure | 1 mmHg ( 190 °C) |
| Stability | 对湿度敏感 |
| Boiling Point | 331°C |
别名和识别编码
| Chemical Name | Zirconium tetrachloride |
|---|---|
| Synonym | 四氯化锆 Zirconium chloride (ZrCl4), (T-4)- Zirkoniumtetrachlorid Zirconium(IV) chloride Zirconium chloride zirconium (IV) chloride Zirconium tetrachloride Zirconium chloride (Zr2Cl8) Tetrachlorozirconium 四氯化锆 Zirkon(IV)-chlorid, wasserfrei 氯化锆(IV) Zirkon(IV)-chlorid wasserfrei Zirkontetrachlorid ZrCl4 Tetrachlorozirconium Zirconium(IV) chloride, anhydrous 氯化锆 |
| CAS Number | 10026-11-6 |
| PubChem Substance ID | 24852962 |
| EC Number | 233-058-2 |
| MDL Number | MFCD00011306 |
| Merck Number | 14,10174 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 氯化锆 |
| LabNetwork Molecule ID | LN00198098 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Materials Science, Metal and Ceramic Science, Salts, Zirconium, Zirconium Salts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Zirconium, Zirconium Salts, 材料科学
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Salts, Zirconium, Zirconium Salts
- {uni_hamburg} no charge; 1fragment
- {SNA} Catalysis an
产品应用
- 用于制金属锆、颜料、纺织品防水剂、皮革鞣剂和分析试剂等。
相关文献及参考
- For a brief feature on uses of this reagent in synthesis, see: Synlett, 1073 (2003).
- Catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyltin hydride, A13298: J. Chem. Soc., Chem. Commun., 2405 (1995); J. Org. Chem., 61, 4568 (1996). Allylstannanes also add trans-selectively to acetylenes under similar conditions: J. Chem. Soc., Chem. Commun., 1513 (1996).
- Highly efficient and reusable catalyst for acetylation of phenols, thiols, amines and alcohols under solvent-free conditions, claimed to be superior to metal triflates: Synlett, 627 (2004).
- Short: II/25A
- Lewis acid. Promotes the rearrangement of hydroxy sulfones to ketones: J. Chem. Soc., Chem. Commun., 2289 (1994).
- Superior catalyst for the Fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures: Tetrahedron Lett., 37, 7659 (1996).
- Merck:14,10174
- In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde: Tetrahedron Lett., 43, 6317 (2002).
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H302 Harmful if swallowed 吞食有害
- H290 May be corrosive to metals 可能腐蚀金属。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S30 Never add water to this product 切勿将水加入该产品中；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S8 Keep container dry 保持容器干燥；
- R37 Irritating to respiratory system 刺激呼吸道
- R14 Reacts violently with water 遇水会猛烈反应
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R35 Causes severe burns 会导致严重灼伤
其他信息
- 易潮解，溶于冷水、乙醇、乙醚，不溶于苯、四氯化碳、二硫化碳。和水反应，生成盐酸和氧化锆。
