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分类

• {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
• {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

• Beilstein:5,329
• Reagent for carboxyl protection in peptide synthesis. Derivatives are stable to HBr, but cleaved by hydrogenolysis: J. Am. Chem. Soc., 81, 5691 (1959); J. Chem. Soc., 4922 (1965). See also 4-Nitrobenzyl­ alcohol, A15742, 4-Nitrobenzyl­ bromide, A15236, and Appendix 6.
• Short: IV/1a
• Short: III/20b
• Reagent for carboxyl protection in peptide synthesis. Derivatives are stable to HBr, but cleaved by hydrogenolysis: J. Am. Chem. Soc., 81, 5691 (1959); J. Chem. Soc., 4922 (1965). See also 4-Nitro
• Short: EINECS
• Has also been used for protection of the thiol group: J. Org. Chem., 37, 3550 (1972); J. Chem. Soc., Chem. Commun., 12 (1974).

安全信息

GHS Symbol

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 280 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 4,66,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1809 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   INHTE5 Inhalation Toxicology.  (Hemisphere Publishing Corp., c/o Taylor &
   Francis Inc., 1900 Frost Rd., Suite 101, Bristol, PA 19007)  V.1-    1989-
   Volume(issue)/page/year: 3,265,1991

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 100 umol/L
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 3,203,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   NTPTB* NTP Technical Bulletin.  (National Toxicology Program, Landow Bldg.
   3A-06, 7910 Woodmont Ave., Bethesda, MD 20205)  Volume(issue)/page/year:
   APR1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,11,1986

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 50 ug/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,11,1986

其他信息

• 下游产品:4-(4-甲基哌嗪-1-基甲基)苯胺
• 用途三:alpha-Chloro-p-nitrotoluene
• 灭火剂:二氧化碳、泡沫、砂土、雾状水。
• 急性毒性:口服-大鼠 LD50: 1809 毫克/公斤
• 包装:25公斤/纸板桶
• 1-(氯甲基)-4-硝基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80091324 4-硝基氯化苄;对硝基氯化苄; 对硝基苯氯甲烷; 对硝基苄基氯; α-氯代对硝基甲苯 25g 81元 2011/04/16 C0229 4-硝基苄氯 4-Nitrobenzyl Chloride 25G 543元 2011/04/16 C0229 4-硝基苄氯 4-Nitrobenzyl Chloride 250G 2800元
• 图谱信息:1-(氯甲基)-4-硝基苯(100-14-1)核磁图( 1 HNMR) 1-(氯甲基)-4-硝基苯(100-14-1)核磁图( 13 CNMR) 1-(氯甲基)-4-硝基苯(100-14-1)Raman光谱 1-(氯甲基)-4-硝基苯(100-14-1)质谱(MS) 1-(氯甲基)-4-硝基苯(100-14-1)红外图谱(IR2) 1-(氯甲基)-4-硝基苯(100-14-1)红外图谱(IR1)
• 类别:有毒物品
• 毒性分级:中毒
• 用途二:用作医药中间体
• TCI Shanghai:4-硝基苄氯 4-Nitrobenzyl Chloride,>;98.0%(GC)(100-14-1)
• 可燃性危险特性:明火可燃; 燃烧释放有毒氮氧化物和氯化物烟雾
• MOL 文件:100-14-1.mol
• Acros Organics:4-硝基苄氯 4-Nitrobenzyl chloride, 99%(100-14-1)
• Alfa Aesar:4-硝基苄氯,99% 4-Nitrobenzyl chloride, 99%(100-14-1)
• 用途一:用于有机合成
• F:4.8-19-21
• MSDS 信息:4-硝基苄氯(100-14-1).msds
• 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
• 外观:白色结晶
• Sigma Aldrich:100-14-1(sigmaaldrich)